Centerville is a city in Montgomery County, Ohio, United States. A core suburb of Metro Dayton, its population was 24,240 as of the 2020 ce…Centerville is a city in Montgomery County, Ohio, United States. A core suburb of Metro Dayton, its population was 24,240 as of the 2020 census. Although the city is located primarily in Montgomery County, a small portion is located in Greene County.
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