SOLVED: 1.41 a. Use the van der Waals equation of state in terms of reduced variables, Eq. (1.4-15), to calculate the pressure of 1.000 mol of CO2 in a volume of 1.000 L at 100.0 °C. The critical constants are in Table A.5 in Appendix A. Since the critical compression factor of carbon dioxide does not conform to the van der Waals value, Zc = 0.375, you must replace the experimental critical molar volume by Vm = (0.375)RTc/Pc.b. Repeat the calculation using the ordinary form of the van der Waals
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